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雙環(huán)辛烯氯化銠二聚體 CAS號:12279-09-3
    發(fā)布時間: 2020-04-21 22:58    

簡介

      Chlorobis(cyclooctene)rhodium dimer is an organorhodium compound with the formula Rh2Cl2(C8H14)4, where C8H14 is cis-cyclooctene. Sometimes abbreviated Rh2Cl2(coe)4, it is a red-brown, air-sensitive solid that is a precursor to many other organorhodium compounds and catalysts.
The complex is prepared by treating an alcohol solution of hydrated rhodium trichloride with cyclooctene at room temperature. The coe ligands are easily displaced by other more basic ligands, more so than the diene ligands in the related complex cyclooctadiene rhodium chloride dimer.

基本信息

中文名稱 雙環(huán)辛烯氯化銠二聚體 英文名稱 Chlorobis(cyclooctene)rhodium(I) dimer
中文別名

雙環(huán)辛烯氯化銠(I)二聚體;氯化雙(環(huán)辛烯)釕;雙(環(huán)辛烯)氯化銠(I)二聚體;

英文別名

Chlorobis(cyclooctene)rhodium(I) Dimer;Chlorobis(cyclooctene)rhodium(I),dimer;[Rh(coe)2Cl]2;cyclooctene,rhodium,dichloride;

CAS號 12279-09-3 分子式 C32H56Cl2Rh2
分子量 717.50400 精確質(zhì)量 716.18700
PSA 0.00000 LOGP 12.96620

物化性質(zhì)

熔點:190oC (dec.)
儲存條件:Freezer

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